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Single walled carbon nanohorns : ウィキペディア英語版
Single-walled carbon nanohorn

Single-walled carbon nanohorn (SWNH) is the name given by Sumio Iijima and colleagues in 1999 to horn-shaped sheath aggregate of graphene sheets. Very similar structures had been observed in 1994 by Peter J.F. Harris, Edman Tsang, John Claridge and Malcolm Green. Ever since the discovery of the fullerene, the family of carbon nanostructures has been steadily expanded. Included in this family are single-walled and multi-walled carbon nanotubes (SWNTs and MWNTs), carbon onions and cones and, most recently, SWNHs. These SWNHs with about 40–50 nm in tubule length and about 2–3 nm in diameter are derived from SWNTs and ended by a five-pentagon conical cap with a cone opening angle of ~20o. Moreover, thousands of SWNHs associate with each other to form the ‘dahlia-like' and ‘bud-like’ structured aggregates which have an average diameter of about 80-100 nm. The former consists of tubules and graphene sheets protruding from its surface like petals of a dahlia, while the latter is composed of tubules developing inside the particle itself. Their unique structures with high surface area and microporosity make SWNHs become a promising material for gas adsorption, biosensing, drug delivery, gas storage and catalyst support for fuel cell. Single-walled carbon nanohorns are an example of the family of Carbon nanocones.
==Synthesis==
SWNHs can be synthesized with high purity by CO2 laser ablation and arc discharge without a metal catalyst. The following two subsections respectively show the representative procedures for the two synthesis methods. The size and purity of the SWNHs can be changed by varying the parameters such as temperature, pressure, voltage and current.

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